step 1 of 5
Added clouds, applied hue/saturation and curves adjustment layers to darken the mood of the image.
step 2 of 5
Added girl to image and used same adjustment layers to darken her. Added shadow to resemble the shadow created by the umbrella.
step 3 of 5
Created rain with noise, motion blur, set to screen, and changed levels. Also, small scattered brush for splashes of rain drops.
step 4 of 5
Duplicated layer, set mode to overlay, blurred layer, and changed opacity to 40%. Added a little yellow and red with color balance.
step 5 of 5
Changed the shadows of the image, they were unnatural to the mood.