i'm thinking
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i'm thinking that 'discussion' is too similar with 'disgusting'...
Last edited by fille on Mon Aug 31, 2009 5:41 pm, edited 1 time in total.
Cheers To The Beautiful Times!
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"Fille" is close to "style"
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you mean 'file', not 'fille'? Cheers To The Beautiful Times!
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i'm thinking i like this emo:
wow! it's really great!!! ![]() Cheers To The Beautiful Times!
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And this one:
And this one: What about this one: ![]() |
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![]() Cheers To The Beautiful Times!
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You win!!
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what? again??? ![]() Cheers To The Beautiful Times!
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I was thinking about ur name >.< Nvm maja is right. You win.
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'fille' will be similar with 'stille': The Stille reaction (aka Stille Coupling) is a chemical reaction coupling an organotin compound with an sp2-hybridized organic halide catalyzed by palladium. The reaction is widely used in organic synthesis. X is typically a halide, such as Cl, Br, I. Additionally, X can be a pseudohalide such as a triflate, CF3SO3-. The Stille reaction was discovered in 1977 (my date of birth) by John Kenneth Stille and David Milstein, a post-doctorate in his laboratory. Stille reactions were used in 50% of all cross-coupling reactions published in 1992. The reaction continues to be exploited industrially, especially for pharmaceuticals. The reaction is usually performed under inert atmosphere using dehydrated and degassed solvent, as oxygen causes the oxidation of the palladium catalyst and promotes homo-coupling of organic stannyl compounds, and these side reactions lead to a decrease in the yield of the desired cross-coupling reaction. As the organic tin compound, a trimethylstannyl or tributylstannyl compound is normally used. Although trimethylstannyl compounds show higher reactivity compared with tributylstanny compounds, the toxicity of the former is about 1000 times larger than that of the latter. Therefore it is better to avoid using trimethylstannyl compounds unless necessary... i'm thinking... Cheers To The Beautiful Times!
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